Publicaciones
(Artículos de Interés) |
PUBLICACIONES MÁS RELEVANTES DEL DR. PASCUAL ROMÁN
PERIODO: 1997–2011
Áreas de investigación
1. Complejos 1D, 2D y 3D con ligandos puentes (oxalato y derivados dicarboxílicos) y ligandos periféricos nitrogenados con propiedades magnéticas.
2. Estudio de la interacción magnética entre iones de metales de transición a través de ligandos puentes aromáticos.
3. Síntesis de compuestos mono- y bidimensionales de coordinación y su procesamiento como nanomateriales.
4. Interación de nucleobases y derivados con sistemas de dimensionalidad variable metal-oxalato. Extrapolación de los resultados a sistemas de interés biológico.
5. Polioxometalatos de híbridos orgánico-inorgánicos. Efectos de la protonación y transiciones de fase.
Publicaciones
Cepeda, Javier; Balda, Rolindes; Beobide, Garikoitz; Castillo, Oscar; Fernández, Joaquín; Luque, Antonio; Pérez-Yáñez, Sonia; Román, Pascual; Vallejo-Sánchez, Daniel.
Lanthanide(III)/Pyrimidine-4,6-dicarboxylate/Oxalate Extended Frameworks: A Detailed Study Based on the Lanthanide Contraction and Temperature Effects. Inorganic Chemistry 2011, 50(17), 8437–8451. DOI: 10.1021/ic201013v . Publication Date (Web): July 29, 2011 (Article). [PDF].
Pérez-Yáñez, Sonia; Beobide, Garikoitz; Castillo, Oscar; Cepeda, Javier; Luque, Antonio; Aguayo, Andrés T.; Román, Pascual. Open-Framework Copper Adeninate Compounds with Three-Dimensional Microchannels Tailored by Aliphatic
Monocarboxylic Acids. Inorganic Chemistry 2011, 50(12), 5530–5532. DOI: 10.1021/ic200560b. [PDF].
Thomas-Gipson, Jintha; Beobide, Garikoitz; Castillo, Oscar; Cepeda, Javier; Luque, Antonio; Pérez-Yáñez, Sonia; Aguayo, Andrés T.; Román, Pascual. Porous supramolecular compound based on paddle-wheel shaped copper(II)–adenine dinuclear entities.
CrystEngComm. 2011, 13, 3301–3305. DOI: 10.1039/C1CE05195D. [PDF].
Goya, Pilar; Martín, Nazario; Román, Pascual. W for tungsten and wolfram. Nature Chemistry, 2011, 3, 336. DOI: 10.1038/nchem.1014. [PDF]
Beobide, Garikoitz; Castillo, Oscar; Cepeda, Javier; Luque, Antonio; Pérez-Yáñez, Sonia; Román, Pascual; Vallejo-Sánchez, Daniel. Low-Nuclearity Mn(II) Complexes Based on Pyrimidine-4,6-dicarboxylato Bridging Ligand: Crystal Structure, Ion Exchange and Magnetic Properties. European Journal of Inorganic Chemistry, 2011, 68–77. DOI: 10.1002/ejic.201000708. [PDF]. Hot Topics Wiley-VCH. Magnetic Materials.
http://www.wiley-vch.de/util/hottopics/magnetic/
Pérez-Yáñez, Sonia; Castillo, Oscar; Cepeda, Javier; García-Terán, Juan P.; Luque, Antonio; Román, Pascual. Supramolecular architectures of metal oxalato-complexes containing purine nucleobases. Inorganica Chimica Acta, 2011, 365, 211–219. DOI: 10.1016/j.ica.2010.09.012. [PDF]
Román, Pascual. El sesquicentenario del Primer Congreso Internacional de Químicos. Anales de la Real Sociedad Española de Química, 2010, 106(3), 231–239. [PDF]
Román, Pascual. Cannizzaro: químico, revolucionario y precursor de la tabla periódica. Anales de la Real Sociedad Española de Química, 2010, 106(2), 137–144. [PDF]
Garcia-Couceiro, Urko; Castillo, Oscar; Cepeda, Javier; Lanchas, Mónica; Luque, Antonio; Pérez-Yáñez, Sonia;
Román, Pascual; Vallejo-Sánchez, Daniel.
Influence of the Synthetic Conditions on the Structural Diversity of Extended Manganese-Oxalato-1,2-bis(4-pyridyl)ethylene System. Inorganic Chemistry 2010, 49(24), 11346–11361.
DOI: 10.1021/ic100928t. [PDF].
Beobide, Garikoitz; Castillo, Oscar; Cepeda, Javier; Luque, Antonio; Pérez-Yáñez, Sonia; Román, Pascual. Condensed heterometallic bidimensional mixed valence CuI/CuII/NiII
cyanidometallate. Dalton Transactions 2009, 9722–9724. DOI: 10.1039/b915284a. [PDF]
Pérez-Yáñez, Sonia; Castillo, Oscar; Cepeda, Javier; García-Terán, Juan P.; Luque, Antonio; Román, Pascual. Analysis of the Interaction between Adenine Nucleobase and Metal-Malonato Complexes. European Journal of Inorganic Chemistry 2009, 26, 3889–3899. [PDF]. Portada [PDF]
Cepeda, Javier; Castillo, Oscar; Garcia-Teran, Juan P.; Luque, Antonio; Pérez-Yáñez, Sonia; Roman, Pascual. Supramolecular Architectures and Magnetic Properties of Self-Assembled Windmill-Like Dinuclear Copper(II) Complexes with Purine Ligands. European Journal of Inorganic Chemistry 2009, 16, 2344 –2353. [PDF]
García-Couceiro, Urko; Castillo, Oscar; Cepeda, Javier; Luque, Antonio; Pérez-Yáñez, Sonia; Román, Pascual; Structural and magnetic characterization of one-dimensional oxalato-bridged metal(II) complexes with 4-amino-3,5-bis(2-pyridyl)-1,2,4-triazole ligand: A supramolecular open-framework. Inorganica Chimica Acta 2009, 362(11), 4210–4218. [PDF]
Ciriano, Miguel A.; Román, Pascual. Breve historia de la traducción del Libro rojo de 2005 de la IUPAC. Panace@ 2008, 9(28), 171–176. [PDF].
Beobide, Garikoitz; Wang, Wen-guo; Castillo, Oscar; Luque, Antonio; Román, Pascual; Tagliabue, Giulia; Galli, Simona; Navarro, Jorge A. R. Manganese(II) Pyrimidine-4,6-dicarboxylates: Synthetic, Structural, Magnetic, and Adsorption Insights. Inorganic Chemistry 2008, 47, 5267–5277. [PDF]
García-Martínez, Javier; Román, Pascual. La Rioja y el aislamiento del wolframio. Diario de La Rioja, La Tribuna de La Rioja, 23/06/2008, p. 23. [PDF]. Blog Ciencia para impacientes: [http://tinyurl.com/3r4xce]
García-Martínez, Javier; Román, Pascual. Spain Celebrates Its Year of Science Honoring Mendeleev. Chemistry International 2008, 30(3), 4–9. [PDF]
García-Martínez, Javier; Román, Pascual. 2007, Año de Mendeléiev: una iniciativa para la divulgación de la química. Anales de la Real Sociedad Española de Química, 2008, 104(1), 50–55. [PDF]. Revista Iberoamericana de Polímeros, 2008 9(4), 451–464 [PDF].
Román Polo, Pascual. Santiago Ramón y Cajal, socio honorario de la SEFQ. Anales de Química 2007, 103(1), 58–64. [PDF]
Garcia-Teran, Juan P.; Castillo, Oscar; Luque, Antonio; Garcia-Couceiro, Urko; Beobide, Garikoitz; Roman, Pascual. Molecular Recognition of Protonated Cytosine Ribbons by Metal-Oxalato Frameworks. Crystal Growth & Design 2007, 7(12), 2597–2600. DOI: 10.1021/cg0705916.
[PDF]
Martín Nazario; Román, Pascual. Mendeléiev: rebeldía y pasión por la ciencia. El País, Sociedad, Futuro, 27/06/2007, miércoles, p. 49. [PDF]
Román, Pascual. Entrevistas. Centenario Mendeléiev -Año de la Ciencia. Elpais.com. 03/07/2007 - 18 respuestas. [HTML]
Román Polo, Pascual. La RSEQ ante el diseño del Plan de Estudios del Grado en Química. Mesa redonda: Diseño del Plan de Estudios del Grado de Química. II Reunión INDOQUIM 2007 (Innovación Docente en Química). pp 13–15. [PDF] [http://webs.uvigo.es/indoquim07]
Beobide, Garikoitz; Castillo, Oscar; Luque, Antonio; Garcia-Couceiro, Urko; Garcia-Teran, Juan P.; Roman, Pascual. Rational design of 1-D metal-organic frameworks based on the novel pyrimidine-4,6-dicarboxylate ligand. New insights into pyrimidine through magnetic interaction. Dalton Transactions 2007, 25, 2669–2680.[DOI] [HTML] [PDF]. [http://tinyurl.com/2t8qfu] CrystEngSelects. 16 August 2007. A selection of recent articles of interest to crystal engineers from across the RSC journals.
Garcia-Teran, Juan P.; Castillo, Oscar; Luque, Antonio; Garcia-Couceiro, Urko; Beobide, Garikoitz; Roman, Pascual. Molecular Recognition of Adeninium Cations on Anionic Metal-Oxalato Frameworks: An Experimental and Theoretical Analysis. Inorganic Chemistry 2007, 46(9), 3593–3602. [DOI] [HTML] [PDF]
Román, Pascual. Mendeléiev, cent anys després. Mètode 2007, 55, 29-34. [PDF]
Luque Arrebola, Antonio; Román Polo, Pascual. La producción científica de los quimicos españoles y el índice h de Hirsch. Anales de Química 2006, 102(2), 11–17. [PDF]
Román Polo, Pascual. Homenaje de Anales a Santiago Ramón y Cajal (1906-2006). Anales de Química 2006, 102(4), 73–78. [PDF]
Román Polo, Pascual . El verdadero nombre del metal tungsten es: wolframio. Apuntes de Ciencia y Tecnología 2006, 18, 25–31. [PDF]
Garcia-Couceiro, Urko; Castillo, Oscar; Luque, Antonio; Garcia-Teran, Juan P.; Beobide, Garikoitz; Roman, Pascual. Rational Design of 2D Magnetic Metal-Organic Coordination Polymers Assembled from Oxalato and Dipyridyl Spacers. Crystal Growth & Design 2006, 6(8), 1839–1847. DOI: 10.1021/cg0601608. [PDF]
García-Terán, Juan P.; Castillo, Oscar; Luque, Antonio; García-Couceiro, Urko; Beobide, Garikoitz; Roman, Pascual. Supramolecular architectures assembled by the interaction of purine nucleobases with metal-oxalato frameworks. Non-covalent stabilization of the 7H-adenine tautomer in the solid-state. Dalton Transactions 2006, 902–911. DOI: 10.1039/b510018f. [ASP] [DOI] [HTML] [PDF]
Beobide, Garikoitz ; Castillo, Oscar; Luque, Antonio; García-Couceiro, Urko; García-Terán; Juan P. ; Román, Pascual. Supramolecular Architectures and Magnetic Properties of Coordination Polymers Based on Pyrazinedicarboxylato Ligands Showing Embedded Water Clusters. Inorganic Chemistry 2006, 45(14), 5367–5382. DOI: 10.1021/ic060221r. [PDF]
Beobide, Garikoitz ; Castillo, Oscar; Luque, Antonio; García-Couceiro, Urko; García-Terán; Juan P. ; Román, Pascual. Reversible dehydration process in a novel three-dimensional covalent network based on pyrimidine-4,6-dionato bridging ligand. Inorganica Chimica Acta, 2006, 359(8), 2583 – 2588. [PDF]
Román Polo, Pascual. Wolframio, sí, tungsteno, no. Anales de Química 2005, 101(2), 42–48. [PDF]
Goya, P.; Román. P. Wolfram vs. Tungsten. Chemistry International 2005, 27 (4), 26–27. [PDF]
Beobide, Garikoitz; Castillo, Oscar; Garcia-Couceiro, Urko; Garcia-Teran, Juan P.; Luque, Antonio; Martinez-Ripoll, Martin; Román, Pascual. A binuclear copper(II) complex containing the pyrazine-2,5-dicarboxylate ligand: Study of the magnetic exchange through the pyrazine bridge. European Journal of Inorganic Chemistry 2005, 13, 2586–2589. [PDF]
García-Couceiro, Urko; Castillo, Oscar; Luque, Antonio; García-Terán, Juan P.; Beobide, Garikoitz;Román, Pascual. One-Dimensional Oxalato-Bridged Metal(II) Complexes with 4-Amino-1,2,4-triazole as Apical Ligand. European Journal of Inorganic Chemistry 2005, 21, 4280–4290. [PDF]
Garcia-Couceiro, Urko; Olea, David; Castillo, Oscar; Luque, Antonio; Roman, Pascual; de Pablo, Pedro J.; Gomez-Herrero, Julio; Zamora, Felix. Scanning Probe Microscopy Characterization of Single Chains Based on a One-Dimensional Oxalato-Bridged Manganese(II) Complex with 4-Aminotriazole. Inorganic Chemistry 2005, 44(23), 8343–8348. [PDF]
Muga, Inaki; Gutierrez-Zorrilla, Juan M.; Vitoria, Pablo; Roman, Pascual; Lezama, Luis; Beitia, Javier I. Unusual two-dimensional nickel(II) complexes based on [Ni(dien)]2+ and [M(CN)4]2- building blocks (M = Ni, Pd and Pt) - synthesis, structural diversity and magnetic properties. European Journal of Inorganic Chemistry 2004, 9, 1886–1893. [PDF]
García-Terán, Juan P.; Castillo, Oscar; Luque, Antonio; García-Couceiro, Urko; Román, Pascual; Lloret, Francesc. One-Dimensional Oxalato-Bridged Cu(II), Co(II), and Zn(II) Complexes with Purine and Adenine as Terminal Ligands. Inorganic Chemistry 2004, 43(18), 5761–5770. [PDF]
García-Terán, Juan P.; Castillo, Oscar; Luque, Antonio; García-Couceiro, Urko; Román, Pascual; Lezama, Luis. An Unusual 3D Coordination Polymer Based on Bridging Interactions of the Nucleobase Adenine. Inorganic Chemistry 2004, 43(15), 4549–4551. [PDF]
Gutierrez-Zorrilla, Juan M.;Román, Pascual. Química e Internet. Algunas direcciones de páginas web útiles para los químicos. Anales de la Real Sociedad Española de Química , 2003, 99(1), 26–35. [HTML] [PDF] [PDF-Anales]
Vitoria, Pablo; Muga, Inaki; Gutierrez-Zorrilla, Juan M.; Luque, Antonio; Román, Pascual; Lezama, Luis; Zuniga, F. Javier; Beitia, Javier I. Water Displacement by Cyanogold Complexes in Binuclear Nickel(II) Compounds Based on Bridging Oxalate. Synthesis, Structural Diversity, Magnetic Properties, and DFT Calculations. Inorganic Chemistry 2003, 42(4), 960–969.
Vitoria, Pablo; Ugalde, Maria; Gutierrez-Zorrilla, Juan M.; Román, Pascual; Luque, Antonio; San Felices, Leire; Garcia-Tojal, Javier. Organic-inorganic hybrids based on four-electron reduced Keggin b-isomer phosphododecamolybdates and diazines. New Journal of Chemistry 2003, 27(2), 399–408.
Muga, Inaki; Gutierrez-Zorrilla, Juan M.; Vitoria, Pablo; Román, Pascual; Lloret, Francesc. Binuclear Ni(II) complexes based on bridging oxalate and tetracyanometallates. Synthesis, crystal structure and magnetic properties. Polyhedron 2002, 21(25–26), 2631–2638.
Castillo, Oscar; Luque, Antonio; Roman, Pascual; Lloret, Francesc; Julve, Miguel. Syntheses, Crystal Structures, and Magnetic Properties of One-Dimensional Oxalato-Bridged Co(II), Ni(II), and Cu(II) Complexes with n-Aminopyridine (n = 2-4) as Terminal Ligand. Inorganic Chemistry 2001, 40(22), 5526–5535.
Luque, Antonio; Sertucha, Jon; Castillo, Oscar; Roman, Pascual. Crystal packing and physical properties of pyridinium tetrabromocuprate(II) complexes assembled via hydrogen bonds and aromatic stacking interactions. New Journal of Chemistry 2001, 25(9), 1208–1214.
Muga, Inaki; Gutierrez-Zorrilla, Juan M.; Vitoria, Pablo; Luque, Antonio; Insausti, Maite; Román, Pascual; Lloret, Francesc. Binuclear nickel(II) complexes based on bridging oxalate and pseudohalides as peripheral ligands: synthesis, crystal structure, DFT calculations and magnetic properties of [{Ni(X)(dien)}2(m-ox)]×nH2O complexes (X = N3-, NCS-, n = 0; NCO-, n = 1). European Journal of Inorganic Chemistry 2000, 12, 2541–2547.
Castillo, Oscar; Luque, Antonio; Sertucha, Jon; Román, Pascual; Lloret, Francesc. Synthesis, Crystal Structure, and Magnetic Properties of a One-Dimensional Polymeric Copper(II) Complex Containing an Unusual 1,1'-Bicoordinated Oxalato Bridge. Inorganic Chemistry 2000, 39(26), 6142–6144.
Castillo, Oscar; Luque, Antonio; Iglesias, Sonia; Vitoria, Pablo; Román, Pascual. Synthesis, crystal structure, thermal behaviour and magnetic properties of a novel one-dimensional copper(II) complex containing neutral and deprotonated 3-hydroxypyridine ligands. New Journal of Chemistry 2000, 24(10), 771–-775.
Sertucha, Jon; Luque, Antonio; Castillo, Oscar; Román, Pascual; Lloret, Francesc; Julve, Miguel. Ferromagnetic coupling through a carbonate bridge in the copper(II) chain [Cu(CO3)(4-apy)2]×H2O (4-apy = 4-aminopyridine). Inorganic Chemistry Communications 1999, 2(1), 14–16.
Unamuno, Iosu; Gutierrez-Zorrilla, Juan M.; Luque, Antonio; Román, Pascual;; Lezama, Luis; Calvo, Rafael; Rojo, Teofilo. Ion-Pair Charge-Transfer Complexes Based on (o-Phenylenebis(oxamato))cuprate(II) and Cyclic Diquaternary Cations of 1,10-Phenanthroline and 2,2'-Bipyridine: Synthesis, Crystal Structure, and Physical Properties. Inorganic Chemistry 1998, 37(25), 6452–6460.
Ugalde, Maria; Gutierrez-Zorrilla, Juan M.; Vitoria, Pablo; Luque, Antonio; Wer, Ana S. J.; Román, Pascual. Synthesis, Crystal Structure, and Thermal Behavior of Organically Templated Three-Dimensional Tunnel Structures Based on a-Keggin Phosphododecamolybdate and Diazines. Chemistry of Materials 1997, 9(12), 2869–2875.
Luque, Antonio; Sertucha, Jon; Lezama, Luis; Rojo, Teofilo; Román, Pascual. Synthesis, characterization and crystal structure of 2-aminopyridinium (2-amino-5-bromopyridine)tribromocuprate(II) and bis(2-aminopyridinium) tetrabromocuprate(II). Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry 1997, 5, 847–854.
Muga, Inaki; Gutierrez-Zorrilla, Juan M.; Luque, Antonio; Román, Pascual; Lloret, Francesc. A Trinuclear Nickel(II) Complex Based on Bridging Oxalate and Cyanide Ligands. Inorganic Chemistry 1997, 36(4), 743–745.
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